Curing rheological properties and process determination of low viscosity epoxy resin for RTM
Keywords:
Resin transfer molding, Epoxy resin, DSC, Viscosity model, Rheological propertiesAbstract
The quality of composite components made by Resin Transfer Molding (RTM) is determined by both the rheological properties of resin and the curing processes. In this paper, the dynamic scanning calorimetry (DSC) method was utilized to study the curing kinetics of a low viscosity SR8100/SD8734 epoxy resin system which is used in aviation engineering. Curing reaction kinetics model was established with the reaction order n being 0.882 and the activation energy being 48.95kJ/mol. By using extrapolation methods, the optimized curing procedure was then determined as 95°C for 36min and then 110°C for 36min. Isothermal viscosity-time of SR8100/SD8734 epoxy resin system was studied with J S Yang’s empirical model, and the analytical results calculated agreed very well with the experimental data in the low viscosity stage(<800mPa·s). Prediction of the RTM processing window for SR8100/SD8734 epoxy resin system was established, which eventually will provide a test method of process optimization and theoretical basis for the application of RTM epoxy resin.
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